In
science,
R is the symbol for the gas constant in the
ideal gas law having a
value of: [1]

Equation etymologyThe first dominant use of
R as a constant in the various
gas laws seems to have been the use by French engineer
Emile Clapyron's use in his 1834
Memoir on the Motive Power of Fire, where he
states that Mariotte’s law (PV = k, at constant temperature) combined with that of Gay-Lussac's law (P = kT, at constant volume), the latter of which being derived by French chemist Joseph Gay-Lussac in 1802, gives the expression: [2]

This is sometimes referred to as the 'G-M law' or the 'law of Marriatte and Gay-Lussac'.
In 1850, German physicist
Rudolf Clausius updated the work of Clapeyron using the 1847 work of French chemist
Henri Regnault, where he reevaluated the content inside of the parentheses, rewriting the gas equation as: [3]

In 1864, Clausius further simplified this expression by using the
absolute temperature scale, conceived by Irish physicist
William Thomson in 1848:
where
t is in degrees centigrade and
T is in Kelvin, such that with substitution in the second previous equation, by 1864 he had arrived at:
The first person to convert R into a universal gas constant, according to American chemistry historian William Jenson, was German chemist
August Horstmann who in 1873 rewrote the previous equation as: [3]

where
u is the "volume of molecular weight [mole] of the
gas" and where R is "the constant for the G-M law with regard to the molecular volume [molar volume]." [5] In this sense, if
u is take as volume per number of particles
n (on the original 1738 use by
Daniel Bernoulli), then we would have:
or

This later version of the equation, with the explicit use of "n" as the number of mols, seems to have been first use in the classic 1923 textbook
Thermodynamics and the Free Energy of Chemical Substances by American physical chemists
Gilbert Lewis and
Merle Randall. [6]
Symbol etymologyThe origin of the symbol R, prior to its 1834 use by Clapeyron, is difficult to pin down. This seems to be due to the fact often early versions of the gas laws were simply stated verbally.
The symbol could have been used in honor of Danish astronomer
Ole Romer who in 1702 built the basic two-fixed point
thermometer; a design later used by
Daniel Fahrenheit in the construction of his thermometer. This, however, is a tentative guess?
In a 2003, chemist William Jenson suggested that
R should be officially named after French chemist
Henri Regnault. [3] On the surface this seems tenible, being that Regnault's
circa 1847 experimental gas work was cited in Irish physicist
William Thomson's famous publication "
An Account of Carnot's Theory of the Motive Power of Heat – with Numerical Results Deduced from Regnault’s Experiments on Steam”, the paper that stimulated German physicist into founding thermodynamics. [4] If one looks at the facts, however, this hypothesis falls apart. Specifically, at the time Clapyron was using
R as a constant in his gas equations of 1834, Regnault was only twenty-four years of age at this point, being a recent graduate of the
École Polytechnique two years prior, having only done work in organic chemistry at this point, and nothing in caloric gas theory. Regnault did not begin his work on the properties of gases and
physics until the 1840s (nearly 15-years after the gas constant R was already in use); his key publication on this subject was in 1847 (and he only began to be cited by
Clausius in 1850). [24] In fact, prior to the work of
Sadi Carnot (1824), there were a number of more dominant investigators on the various
gas laws:
Alexis Petit (1818),
Joseph Gay-Lussac (1800),
Jacques Charles (1787),
Daniel Bernoulli (1738), Edme Mariotte (1679), Henry Power (1661),
Robert Boyle (1660),
Robert Hooke (1657).
References1. Daintith, John. (2005).
Oxford Dictionary of Physics. Oxford University Press.
2. Clapeyron, Émile. (1834). “Memoir on the Motive Power of Heat”,
Journal de l’Ecole Polytechnique. XIV, 153 (and Poggendorff's
Annalender Physick, LIX, [1843] 446, 566).
3. (a) Jensen, William B. (2003). “The Universal Gas Constant R” (
abstract: “this column traces the history of the gas constant R and the probable reason for its representation by the letter R.),
J. Chem. Edu. 80: 731.
(b)
William B. Jensen (faculty) – Department of Chemistry, University of Cincinnati.
4. Clausius, Rudolf. (1850). “On the Moving Force of Heat and the Laws of Heat which may be Deduced Therefrom” (
pg. 21), Communicated to the Academy of Berlin, Feb.; Published in Poggendorff’s
Annalen, March-April, Vol. lxxix, pgs. 368, 500, and Translated in the
Philosophical Magazine, July 1851, Vol. ii. pgs. 1, 102.
5.
Horstmann, August F. (1973). “Theorie der Dissociation”, Liebig’s Annalen der Chemie und Pharmacie, Bd. 170 (CLXX), 192-210. 6.
Lewis, Gilbert N. and Randall, Merle. (1923). Thermodynamics and the Free Energy of Chemical Substances, McGraw-Hill Book Co., Inc. External links●
Gas constant – Wikipedia.