In
mechanics,
statistical mechanics is study of properties of
matter in
equilibrium, a subject derived from the
kinetic theory interpretation of the
laws of thermodynamics, applied generally to gases, albeit formulated from an
a priori point of view, i.e. derived or reasoned from self-evident propositions. [1]
Etymology In 1749, German scholar Gottfried Achenwall suggested that since ‘science’ dealt with the natural ‘states’ of society, it should be called
statistik. [6]
The term “statistical mechanics” was coined by Scottish physicist
James Maxwell in 1878. [2] In 1892, Gibbs wrote English physicist
John Strutt with characteristic modesty: [3]
"Just now I am trying to get ready for publication something on thermodynamics from the a priori point of view, or rather on 'Statistical Mechanics' . . . I do not know that I shall have anything particularly new in substance, but shall be contented if I can so choose my standpoint (as seems to me possible) as to get a simpler view of the subject."
Supposedly, by the term
a priori Gibbs meant related to or derived by reasoning from self-evident propositions. In any event, ten years later this work resulted in a classic book,
Elementary Principles in Statistical Mechanics (1902), which has since been called the "bible of statistical physics", which put statistical mechanics on a new and more general basis. [4]
Versus statistical thermodynamicsTreatises on statistical mechanics, as compared to
statistical thermodynamics, according to
Ralph Fowler and
Edward Guggenheim, are nearly synonymous in content, albeit the former tend to contain considerable sections of purely physics or astrophysical interest, with many passages devoted entirely to mathematical details of proofs, with deliberate avoidance of the use of ordinary thermodynamic methods. [1]
Human thermodynamicsIn 1952, English physicist
C.G. Darwin, in his 1952 book
The Next Million Years, argued that statistical mechanics could be used to study and predict human history, and that his would define the subject of
human thermodynamics. In short, he argued that in order to logically predict human history, one would first need to define the person as a point
molecule or
human molecule and to model human social systems as "conservative dynamical systems" such that when human molecules collide there exists a conservative nature to the
interaction and that both internal and external parameters must be accounted for in a statistical thermodynamic analysis of any
human system. [5]
References1. Fowler, Ralph and Guggenheim E.A. (1939).
Statistical Thermodynamics: a version of Statistical Mechanics for students of Physics and Chemistry (
pgs. vii-viii). The MacMillan Co. (1943 second edition).
2. Ebeling, Werner and Sokolov, Igor M. (2005).
Statistical Thermodynamics and Stochastic Theory of Nonequilibrium Systems (ch. 1.2:
On history of fundamentals of statistical thermodynamics, pgs. 3-12). World Scientific.
3.
Josiah Willard Gibbs (1829-1903) – AIP.org.
4. Gibbs, J. Willard (1901).
Elementary Principles in Statistical Mechanics - Developed with Special Reference to the Rational Foundation of Thermodynamics. New York: Dover.
5. Darwin, Charles G. (1952). The Next Million Years (pg. 26). London: Rupert Hart-Davis.6. Ball, Philip. (2004).
Critical Mass - How One Thing Leads to Another (pg. 53).
New York: Farrar, Straus and Giroux.
Further reading ● Ma, Shang-Keng (1985).
Statistical Mechanics. Philadelphia: World Scientific.
External links●
Statistical mechanics – Wikipedia.